I take it this is the incomplete engine in your other post?
If both cylinders are to be the same bore, it is not really a compound.
For 1/2 inch bore the piston length could perhaps be anything from 1/4 to 1/2 or a bit longer, depending on how you intend to seal it – for a low working pressure you could make it long, and just put some oil grooves in.
Clearances are not going to be critical on something like that – aim for 1/32 each end, but 1/16 will not hurt.
Since you have the original valve gear, I would work out the valve travel and port face dimensions alongside designing the cylinder, and this should give you a few clues to the original proportions.
Mill engines usually had quite long cylinders, and bear in mind the rear cover needs to be fairly long to accommodate the gland.
It looks quite lightly built, so do not try and extract too much power from it!
Just my opinion.