It may be that the slots, and / or the jaws are dirty or burred.
Having cleaned everything, rotate the three jaw chuck until No 1 slot is easily visible. use the chuck key to rotate the scroll until the start of the scroll just becomes visible
Enter No 1 jaw, and rotate scroll to engage the jaw.
Continue rotating the scroll to repeat for Jaw 2 and then for Jaw 3.
When fully rotated, the scroll should bring all three jaws to the centre. If this does not happen, either you have engaged one of the jaws in the scroll at the wrong time, or one of the jaws may have the first "tooth" broken off.
This is not a complete disaster. If you ensure that the damaged jaw engages with the scroll at the second rotation of the scroll, all three Jaws should arrive at the centre at the same time.
But do not expect absolute concentricity from a three jaw chuck. A good one will hold work to slightly better than 0.005" (0.127 mm ) T I R. A badly worn one could five times worse! You just need to be aware and make allowances for this.
Howard